Sulfonyl chlorides as an efficient tool for the postsynthetic modification of Cr-MIL-101-SO3H and CAU-1-NH2.

نویسندگان

  • Arne Klinkebiel
  • Nele Reimer
  • Martin Lammert
  • Norbert Stock
  • Ulrich Lüning
چکیده

Postsynthetic modification can be used to introduce sulfonamide functionalities into MOF frameworks. Using sulfonyl chlorides as reactive intermediates, Cr-MIL-SO3H and CAU-1-NH2 have been further modified to give hitherto unknown functionalized MOFs in which a sulfonamide group is bound to the framework either by its N or its S atom.

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عنوان ژورنال:
  • Chemical communications

دوره 50 66  شماره 

صفحات  -

تاریخ انتشار 2014